GeoClassroom Physical Geology Historical Geology Structure Lab Mineralogy Petrology

Amphiboles

Generally: W0-1X2Y5Z8O22(OH, F, Cl)2

W: 12-fold coordination - ions can't fit (A1 site) Na+, Ca2+ - coordination with OH- in some cases

X: 6-8 fold site (M4 site)
Ca2+, Na+, Mn2+, Fe2+, Mg2+, Li+

Y: M1, M2, M3 possibilites - 6CN - only slightly distorted
Mg2+, Fe2+, Fe3+, Al3+, Ti4+ (only Ca can't fit here)

Z: typical tetrahedral - 4-fold
usually Si42+, Al3+ - rarely anything else




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